ZA4800

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A polarized Zeeman atomic absorption spectrophotometer — 4 models for flame, graphite furnace, or both methods, with an optional hydride method for As/Se/Sb.

 

  • Polarized Zeeman background correction (permanent magnet) on all models — a single correction method for all elements, including those a D2 lamp cannot correctly correct (e.g. sodium, potassium)
  • Dual-detector system — sample and reference light are measured simultaneously by independent detectors, reducing baseline noise and increasing correction accuracy
  • Wavelength range 190 – 900 nm (Czerny-Turner optics, 1.800 lines/mm, automatic spectral peak positioning) — covers over 50 elements via single-element and multi-element hollow cathode lamps
  • Wizard software with voice guidance, automatic instrument diagnostics (wavelength precision, baseline stability, sensitivity, repeatability), and data import from Excel (Load Sample Table)
ZA4800

Rapid sequential flame model

  • Sequential measurement of up to 12 elements from a single sample injection
  • A new diffraction grating drive mechanism — up to ~30% faster than the conventional flame method (e.g. 6 elements / 20 samples: 48 min instead of 68 min, per the brochure)
  • 8 lamps (turret), 4 lit simultaneously (versus 2 on the other three models) — shorter lamp stabilization time
  • Dimensions 800 × 650 × 567 mm, weight 104 kg · power supply 115/220/230/240 V, 0,2 kVA (consumption up to 0,1 kW)
  • Intended use: laboratories that routinely measure multiple elements per sample and need higher sample throughput

 

Details

  • Applications: environment (wastewater/river/seawater, soil — heavy metals down to ppb levels), food (cereals, dairy products, beverages, additives — Na, K, Ca, Fe, Pb, Cd), agriculture (fertilizers, animal feed — K, Ca, Mg, with an optional hydride method for As/Se), energy (lead in gasoline, major and trace metals in lithium-ion battery materials), plating (major constituents and trace metals in baths, e.g. copper in a nickel bath), materials (impurities and toxic metals in paints, plasticizers, batteries, cellulose, bottle leaching), pharmaceuticals (residual catalyst and toxic metals)
  • Elements: over 50 metals/metalloids via single-element hollow cathode lamps (Ag, Al, As, Au, B, Ba, Be, Bi, Ca, Cd, Co, Cr, Cu, Fe, Ga, Ge, Hf, Hg, In, Ir, K, La, Li, Mg, Mn, Mo, Na, Nb, Ni, Pb, Pd, Pt, Rh, Ru, Sb, Sc, Se, Si, Sn, Sr, Ta, Te, Ti, Tl, V, W, Y, Yb, Zn, Zr) plus multi-element lamps (e.g. Ca-Mg, Cd-Pb, Cd-Zn, Cu-Fe-Ni, Fe-Mn-Ni, Cu-Fe-Mn, Cr-Cu-Mn, Cu-Mn-Si, Cr-Cu-Fe-Mn-Ni, Co-Cr-Cu-Fe-Mn-Ni)
  • Flame accessories (ZA4000, ZA4300, ZA4800): High-Temperature Burner Head (for Al, B, Be, Ge, La, Nb, Si, Ta, Ti, V, W, Zr with an N₂O-acetylene flame), High Salt Burner Head (high-salt samples, resistant to aqua regia), Glass Atomizer Set, Heated Quartz Cell (with the hydride method), SSC-230 Flame Autosampler (up to 80 samples, up to 12 elements), HFS-4 Hydride Formation System (As, Se, Sb with NaBH₄), PFA Disperser (samples with HF), Micro-Sampling Kit (samples <0,5 mL), Mercury Analyzer (mercury, cold-vapor method)
  • Graphite furnace accessories (ZA4000, ZA4700): several cuvette types (Pyro Tube CIIHR/DIIHR/HR, Graphite Tube HR, Cup-type cuvette HR), Dustproof Cover, LED furnace work lighting, Alternate Gas Unit (argon + oxygen for decomposing organic material), GA Autosampler PEEK Nozzle, OMEGA Platform (for large sample volumes), automatic dosing of up to 4 types of chemical modifiers; Independent Atomizer (independent flame/graphite atomizers) available only on the ZA4000 model
  • Safety functions (flame models): automatic gas-leak check at ignition, automatic gas-supply shutoff when the flame goes out, flashback prevention (buffer tank method), flame monitoring (flame sensor), fuel and auxiliary gas pressure monitoring, burner high-temperature interlock, drain liquid level and cooling water flow monitoring
  • Software: wizard measurement parameters, automatic instrument diagnostics (wavelength precision, baseline stability, sensitivity, repeatability), continuous monitoring (numerical data, working curve, instrument status), batch display of atomization profiles, Excel sample table import (Load Sample Table), QC functions (sample check, STD check, QC sample check, calibration curve check, recovery check)

 

Analytical method ZA4000: flame/graphite furnace (tandem) · ZA4800: flame (rapid sequential) · ZA4300: flame · ZA4700: graphite furnace
Measurement mode Atomic absorption and emission — all models
Measurement method / background correction Double beam method, polarized Zeeman background correction — all models
Optics Czerny-Turner mount, 1.800 lines/mm, blaze 200 nm; focal length 400 mm / reciprocal dispersion 1,3 nm/mm — all models
Wavelength range 190 – 900 nm, automatic spectral peak positioning — all models
Slit width 4 settings: 0,2 / 0,4 / 1,3 / 2,6 nm — all models
Detector Photomultiplier tube (PMT) × 2 — all models
Lamps 8 lamps (turret system); ZA4000/ZA4300/ZA4700: 2 lit simultaneously · ZA4800: 4 lit simultaneously; lamp current 1,0 – 20 mA (average value)
Zeeman-effect magnet Flame section (ZA4000/ZA4300/ZA4800): 0,9 T permanent magnet · Graphite furnace section (ZA4000/ZA4700): 1,0 T permanent magnet
Burner (flame models) Premixed “fishtail” type, automatic setting of combustion gas flow
Furnace (graphite models) Temperature control 50 – 2.800°C (up to 2.900°C only for the “clean” phase with Pyrotube CIIHR/DIIHR); optical or current-based heating control
Autosampler (graphite models) Up to 60 samples (96-well microplate optional); injection of 1 – 100 µL in steps of 1 µL; 5 injection speeds; automatic standard dilution
External dimensions (W×D×H) / weight ZA4000: 1.100×650×637 mm / 188 kg · ZA4800: 800×650×567 mm / 104 kg · ZA4300: 800×650×567 mm / 104 kg · ZA4700: 800×650×637 mm / 137 kg
Power supply ZA4000/ZA4700: 220/230/240 V, 7,5 kVA (consumption up to 4,1 kW) · ZA4800/ZA4300: 115/220/230/240 V, 0,2 kVA (consumption up to 0,1 kW); 50/60 Hz — all models
Computer Windows 11 Pro, 64-bit — all models
Elements Over 50 metals/metalloids via single-element hollow cathode lamps, plus multi-element lamps (see the list above)

Source: hitachi-hightech.com/global/en/products/analytical-systems/aas/za4000.html (series description, 4 models, technology, applications) and “Hitachi_AAS_ZA4000 (002).pdf” (Hitachi High-Tech, part no. HSS-E041P, 2024.8 edition, internal archive in “Brošure MICROMERITICS/”